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orbitals of the product fragments and the states which arise from them are shown in Figure 15.6. The reaction is again considered to take place in the plane of the carbonyl group and the orbitals are symmetry typed according to their behavior with respect to re ection in this plane. A Dauben Salem Turro state correlation diagram for the photochemical step of the Norrish Type I cleavage reaction is shown in Figure 15.7. The reactant (carbonyl) states are classi ed in point group Cs and also as S or A. The state correlation diagram indicates that the reaction should proceed most e ciently via the triplet pp state which correlates directly with the ground state of the products. The 3 np state of the carbonyl group also cleaves relatively e ciently via internal conversion at the crossing of the triplet surfaces. Reaction via 1 np also occurs since the 1 np state correlates with a higher singlet electronic state of the products and can then undergo internal conversion and vibrational cascade to the lowest singlet state of products. However, in this case, recombination of the radical pair is very fast if the radicals have been held together in a solvent cage or within the same fragment, as in the case of -cleavage of cyclic ketones. The carbonyl ground state correlates with the 1 D1 state of products. This reaction corresponds to thermal cleavage of the C C bond.

Here it is assumed that the light source is at the center of curvature. This approximate method has proved to be very accurate for most practical purposes. Examples of computed null Ronchi rulings are given in Figure 9.10. Figure 9.11 shows a normal and a null Ronchigram. It is evident that the fringes, in addition to being straight, are much better de ned in the null test [Fig. 9.11(b)]. A disadvantage of the null test, as compared to the normal test, is that the ruling must be positioned very precisely on the calculated place along the optical axis when the test is made. The reason is that the asphericity compensation depends very critically on that position. To draw a circle on the ruling so that its projection on the mirror coincides with the outer edge of that surface is of great help.

2 4 I (bilAlHz)

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The book s companion Web site, www.theserverside.com/patterns/ejbpatterns, contains the book s running/compiling source code examples, as well as a readers discussion forum. This Web site will also hopefully be continuously evolving, with more patterns added to it over time from the community.

Ovals are the recommended shape for pages. This is because the design is conceptual at this point and the other icons are more like real pages. Choose the item label that works best for you. A page title that says welcome doesn t tell you anything about the page, because only welcome shows, so consider another title for the duration of your prototyping. The file name for your pages will tend to be something like products1.html at first, but you ll be changing names after you create the page objects. The design name label requires that you hand-name each page object after you add it.

case that s something like a CD jewel case. The caddy is hinged on one side and opens so that a disc can be placed inside. The caddy has a sliding metal cover on its bottom that slides out of the way when the caddy is inserted into the CD drive. With the sliding cover open, the laser can access the disc. When the CD is inserted into the caddy and placed inside the drive, the effect is very much like the action of a 3.5" floppy disk.

Ehlers and van Rensburg (1996) Fukunaga et al. (1997)

Counterfeit websites use deception as the attack vector. They are intended to look genuine, but are used to extract personal information from the visitor. Often they re used in conjunction with spam and pop-up pages to install spyware, adware, hijackers, dialers, Trojans, or other malware. It can all happen as quickly as the web page loads, or you may be attacked when you click a link.

In the previous chapter, you learned about the architecture of XSQL. You looked at a lot of diagrams, but you did not write any code. In this chapter, you start coding. The first step is to flesh out your knowledge of the xsql:query action, which you used in previous examples. This is the action used to retrieve data from the database using SQL statements. This is only one of the built-in actions, though. All of them are covered in this chapter. But before going in to the rest of the actions, you will learn about the canonical XSQL schema and date formatting. These two areas apply generally to several of the built-in actions, including xsql:query. The chapter ends by describing how to link to XSLT stylesheets. This chapter provides all of the raw information for using the built-in XSQL actions. A couple of the areas, however, are explored in more detail in later chapters. Passing parameters between pages is very important, and is covered in 6. The actions that allow you to put information into the database are covered here, but an in-depth discussion of how to modify your database is presented in 7. You will learn how to create your own custom actions in 18.

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